PRODUCT BULLETIN
Safety Factors
Clear Gel Candle Formulations
Today's candle market is experiencing a tremendous growth
due to the increased popularity of and uses for candles. One of the most
unique, versatile and attractive candles available is the "clear gel candle"
Clear gel candles are available in a combination of sizes and shapes, and
may include fragrances and colors, as well as unique design elements. Clear
gel candles may also be formulated for a variety of consumer purposes.
Similar to traditional wax candles, clear gel candles
are commonly produced from a hydrocarbon base stock. The use of a gelled
hydrocarbon base stock provides the additional advantage of transparency.
Penreco produces and markets a series of patented gels (US Patent 5,879,694)
for use in the manufacture of clear gel candles under the Versagel™
brand name. These gels may be custom formulated to incorporate fragrances,
finely dispersed decorations, and other active and/or inert components.
While Penreco does not manufacture candles and is not
an expert in the field of candle manufacturing, it has, as a service to
its customers, prepared a list of factors which should be considered by
a candle manufacturer before formulating a clear gel candle. Penreco
has compiled this list of criteria, which are identified as "Safety Factors,"
from candle industry data and resourses, and internal evaluations of clear
gel candle formulations.
This is not intended to be a comprehensive list of factors
to be taken into consideration when formulating a clear gel candle. It
also does no eliminate the need for the candle manufacturer to perform
strict safety tests concerning the burning and flaming characteristics
of any candle.
Safety Factor List
-
Formulation Ingredient - Gel
Penreco sells a series of candle gels under the Versagel™ brand
name. They are formulated with a narrow cut hydrocarbon oil of exceptional
safety relative to the flash point. Via the with a narrow cut hydrocarbon
oil of exceptional safety relative to the flash point. Via the COC method,
flash points of 430ºF and sustained burn (Fire Point) of 500ºF
are typical. Penreco also has optimized polymer type and concentration
to produce a gel of exceptional clarity and maximized viscosity to resist
cold flow of the gel in the container of choice. Each Versagel™ grade is
designed for different fragrance capacity with Versagel™ CLP designed for
fragrance loads of 0-3%, Versagel™ CMP designed for fragrance loads of
3-5%, and Versagel™ CHP grade designed for suspension of ingredients such
as glitter, and specialty pigments along with up to 6% fragrance.
-
Formulation Ingredient - Fragrance
Penreco does not sell fragrances but has developed excellent relationships
with several of the leading fragrance companies. Fragrance selection becomes
critical as it relates to compatibility or solubility in the gel. Each
fragrance is a complex mixture of many aroma chemicals, perhaps 30-50 different
chemical ingredients, combined to produce a fragrance in which the polarity
of the mixture needs careful consideration.
A fragrance with a non-polar (hydrocarbon compatible) character is
most preferred. This non-polar character does not deteriorate the gel strength
and has excellent solubility. The second variable in fragrance selection
is the fragrance's flash point. Most fragrances have flash point of 140ºF
and higher. A most preferred fragrance flash point would be 170ºF
or higher. In summary, the fragrance types to most avoid would be polar
fragrances with flash points below 170ºF. A quick check for fragrance
polarity can be done with mineral oil. A non-polar fragrance should be
100% soluble (with no separation) in mineral oil at the following ratios:
25% fragrance / 75% Mineral oil
75% fragrance / 25% Mineral oil
-
Formulation Ingredient - Dyes
No information has been found which shows that the dye influences
candle safety.
-
Formulation Processing or Mixing
When processing the Versagel™ candle gel series, Penreco has insure
that the polymer concentration is uniform throughout the gel. Care must
be taken in not only selecting the correct fragrance but also in completely
and uniformly mixing the fragrance into the gel before packaging the gel
into the container. Incomplete mixing of the fragrance can cause an irregularly
burning flame.
-
Gel Candle Wicks
Penreco does not sell wicks or make wick recommendations for final
consumer packages. We believe the slower burn rate of gelled candle technology
(perhaps 40-50% slower than wax) may, unfortunately, encourage manufacturers
to use "oversized" wicks.
Prewicked wick systems are available with the wick attached to a
20mm metal clip. Wick sizes are diverse and must be test burned by the
manufacturer to make sure they work with the gel and additive combination.
Different sized containers and additive combinations (colors, specialty
pigments, fragrance load, etc.) can effect how the candle will burn. These
wicks and tabs can be manufactured to any length and wick size up to 2mm
in thickness including the wax coating. Wick length and placement
are important details that can contribute to candle safety. Wicks not trimmed
to less than ¼ inch creates a potential for a very large flame with
non-uniform combustion, which, when no centered properly, can create localized
overheating of the container and "pool". Such conditions can cause uneven
temperature dissipation, a potentially unsafe condition.
-
Gel Candle Containers
Penreco has studied and burned countless experimental candles in
containers, jars, glasses, and mugs of different sizes and shapes. As mentioned
in the wick choice, the characteristics of the "pool viscosity" and pool
temperature are influenced by the wick size and container selection. Container
diameter will influence "pol temperature" and can hinder the safe dissipation
of generated heat. The container also becomes important at the end of the
burn cycle during the burning of the last few grams of candle gel. Therefore
container composition (glass, tempered glass, clay, etc.), container center
of gravity and base stability, and container diameter are all factors to
be considered.
-
Gel Candle Consumer Use Instructions
Penreco feels proper consumer education to also be an important
aspect of gel candle safety. Points are as follows.
1. Never burn a candle unattended
2. Never burn for more that four hours
3. Always trim wick to ¼" above the
gel surface before use.
4. Never burn the last inch of a candle.
In summary, we have attempted to identify key safety factors. However,
this report should not be construed by the manufacturer as license to bypass
clear and decisive safety testing of all variables before launch.
Guidelines to
assist in the handling of Versagel™ C
|
Physical Process
|
Temp °F
|
Temp °C
|
| Mixing and blending other
ingredients into the gel |
203-221
|
95-105
|
| Pouring the candle gel
from one container into another |
185-203
|
85-95
|
| Loss of air bubbles |
167-185
|
75-85
|
| Stiffening of the liquid
product into a gel structure |
140-167
|
60-75
|
| Oven temperature for the
removal of air bubbles from the gel |
131-158
|
55-70
|
-
Please note that
these temperatures are estimates only, and may need to be adjusted by as
much as ± 10 °C (20°F).
-
The inclusion of
fragrance or other materials will affect the properties listed above.
-
These temperatures
may need to be modified depending on the flash points of the added ingredients.
-
When adding fragrances
or other soluble ingredients to the gels, the blend should be thoroughly
mixed to ensure that the resulting gel is completely uniform and homogeneous.
These
temperature ranges have been developed from our experience in the lab while
working with the candle gels and should not be considered recommendations
for manufacturing conditions. In a manufacturing environment, other factors
may be important which cannot be predicted or simulated in a laboratory.
|
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